Manufacture of Mesoporous Silicon from Living Plants and Agricultural Waste: An Environmentally Friendly and Scalable Process

• Published in: SILICON 2012-10, Vol.4 (4), p.259-266
• Main Authors: Batchelor, L., Loni, A., Canham, L. T., Hasan, M., Coffer, J. L.
• Format: Article
• Language: English
• Subjects: Agricultural wastes; Bamboo; Chemistry; Chemistry and Materials Science; Environmental Chemistry; Inorganic Chemistry; Lasers; Magnesium; Materials Science; Optical Devices; Optics; Original Paper; Photonics; Photovoltaic cells; Polymer Sciences; Porous silicon; Silicon; Silicon dioxide; Sintering (powder metallurgy); Solar cells; Sugarcane
• ISSN: 1876-990X; 1876-9918
• DOI: 10.1007/s12633-012-9129-8

We demonstrate a process for realising mesoporous silicon from a range of land-based plants such as common grasses, bamboos, sugarcane and rice. Such plants act as “natural factories”, converting and concentrating vast quantities of soluble silicon in soil into nanostructured forms of silica in their roots, stems, branches or leaves. This porous biogenic silica is chemically extracted and then thermally reduced to porous silicon using magnesium vapor. Importantly, for larger batch size, an inexpensive thermal moderator such as salt, is added for control of the reaction exotherm and minimization of sintering. Mesoporous silicon of >350 m 2 /g with 8 nm wide pores has been obtained from a bamboo extract, for example. The same process is applicable to a wide range of “silicon accumulator plants”. The purity of this “naturally derived” porous silicon is likely to be raised to a level acceptable for a wide range of high volume applications outside of electronics and solar cell technology.