Synthesis of diallyl acetals from allyl alcohol and paraformaldehyde or 1,3,5-trioxanes

The solvent-free reaction of 1,3,5-trioxane or paraldehyde with allyl alcohol under mild conditions afforded diallyloxymethane and 1,1-diallyloxyethane in up to 98% yields. The TsOH—CaCl 2 (anhydrous) catalytic system used in the reaction allowed generation of HCl during the process. The use of para...

Full description

Saved in:
Bibliographic Details
Published in:Russian chemical bulletin 2023-12, Vol.72 (12), p.2908-2912
Main Authors: Kazantsev, D. A., Denisov, A. A., Koryakova, O. V., Ezhikova, M. A., Kodess, M. I., Pestov, A. V.
Format: Article
Language:English
Subjects:
Acetals
Calcium chloride
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The solvent-free reaction of 1,3,5-trioxane or paraldehyde with allyl alcohol under mild conditions afforded diallyloxymethane and 1,1-diallyloxyethane in up to 98% yields. The TsOH—CaCl 2 (anhydrous) catalytic system used in the reaction allowed generation of HCl during the process. The use of paraformaldehyde instead of 1,3,5-trioxane increased the yield of diallyloxymethane up to 98%.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-4100-y