Corrosion Resistant Multilayered Electrode Comprising Ni3N Nanoarray Overcoated with NiFe‐Phytate Complex for Boosted Oxygen Evolution in Seawater Electrolysis

• Published in: Advanced energy materials 2024-02, Vol.14 (8), p.n/a
• Main Authors: Li, Ping, Zhao, Shien, Huang, Yuqi, Huang, Quhua, Xi, Baojuan, An, Xuguang, Xiong, Shenglin
• Format: Article
• Language: English
• Subjects: Anodes; chloride‐corrosion resistance; Coordination compounds; Corrosion; Corrosion prevention; Corrosion products; Corrosion resistance; Electrode materials; Electrodes; Electrolysis; Electron states; Electron transfer; Engineers; Intermetallic compounds; Iron compounds; Mass transfer; Metal foams; metal‐phytate complex; nanoarray electrode; Nickel compounds; Oxygen evolution reactions; Phytic acid; Protons; Saline water; Seawater; seawater electrolysis; transition metal nitride
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.202303360

Engineering high‐performance oxygen evolution reaction (OER) anode material with high activity, selectivity, and strong robustness against chloride corrosion is critical to advance seawater electrolysis for large‐scale production of H2, yet a daunting challenge. Herein it is reported for the first time, the engineer of a multilayered electrode consisting of Ni foam‐supported Ni3N porous nanosheet array decorated with NiFe‐phytate coordination complex overlayer (NF/Ni3N@NiFe‐PA) via a facile interfacial coordination assembly, for remarkably boosted and sustained OER in alkaline seawater electrolysis. Benefitting from regulated electronic state by synergism between Ni and Fe species, boosted proton‐coupled electron transfer via accelerating proton movement with the aid of incorporated phytic acid as proton transfer relay, and promoted mass transfer rendered by unique superhydrophilic and superaerophobic property, the resulting NF/Ni3N@NiFe‐PA demonstrates prominent OER activity in seawater. Impressively, integrating anticorrosive Ni3N with NiFe‐PA complex and in situ generated NiFeOOH can collaboratively contribute to chloride repelling, leading to exceptional corrosion resistance of the electrode. This work affords a novel paradigm to engineer active and corrosion‐resistive anode for selective OER in saline water electrolysis via simultaneous geometric and electronic structural manipulation. A multilayer‐architectural electrode consisting of NiFe‐phytate complex overlayer decorated on Ni3N nanoarray is engineered via interfacial coordination assembly. Benefitting from the regulated electronic state, boosted proton‐coupled electron transfer, promoted mass transfer kinetics, and special multilayered configuration available for chloride repelling, NF/Ni3N@NiFe‐PA performs as a remarkably active, corrosion‐resistant, and OER‐selective anode for seawater electrolysis.