3-Aminofuro[2,3-b]pyridines: Reaction with N-Chlorosuccinimide and Sodium Hypochlorite

The reaction of aminoamides of the furo[2,3- b ]pyridine series with an aqueous solution of sodium hypochlorite and N -chlorosuccinimide was studied. It was found that the chlorination reaction proceeds at position 2 of the furopyridine system, leading to previously unknown 3-imino-2-chlorofuro[2,3-...

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Bibliographic Details
Published in:Russian journal of general chemistry 2024-02, Vol.94 (2), p.314-326
Main Authors: Stroganova, T. A., Vasilin, V. K., Shitikov, N. V., Dmitrieva, I. G., Krapivin, G. D.
Format: Article
Language:English
Subjects:
Aqueous solutions
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Pyridines
Sodium hypochlorite
Substitution reactions
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Summary:The reaction of aminoamides of the furo[2,3- b ]pyridine series with an aqueous solution of sodium hypochlorite and N -chlorosuccinimide was studied. It was found that the chlorination reaction proceeds at position 2 of the furopyridine system, leading to previously unknown 3-imino-2-chlorofuro[2,3- b ]pyridine-2-carboxamides. For some synthesized compounds, nucleophilic substitution reactions were investigated. Among the obtained substances, compounds were identified that have antidote activity against 2,4-D.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363224020075