Accurate measurement of micro gas flow rates for comprehensive evaluation of polymeric membranes applicable in gaseous separations

• Published in: Separation science and technology 2024-03, Vol.59 (5), p.799-820
• Main Authors: Shiva Prasad, N., Atkar, Aarti, Sridhar, Sundergopal
• Format: Article
• Language: English
• Subjects: asymptote fitting; Binary mixtures; Carbon dioxide; Defects; Evaluation; Flow rates; Flow velocity; Gas flow; Gas permeation; Gas separation; isochoric apparatus; Membrane permeability; membrane solubility; Membranes; Permeability; Permeation; surface defects; Thin films; Transport properties
• ISSN: 0149-6395; 1520-5754
• DOI: 10.1080/01496395.2024.2346753

The time-lag method is the most useful technique to determine gas permeability, diffusivity, and solubility. However, it is difficult to evaluate the transport properties of the membrane accurately because gas permeability depends on the technique used to assess gas flow. The significance of the present study is to design an economic isochoric apparatus to accurately measure micro-range gas flow rates ranging from 10 −6 to 10 cm 3 (STP) s −1 . A strategic procedure is demonstrated to eliminate possible artifacts while conducting the gas permeation experiments, including utilizing downstream pressure rise profiles to identify nanoscale defects as well as transient and steady-state permeation. An indigenous apparatus was developed to estimate the polymeric intrinsic properties of the dense and thin-film composite membranes. The device has been successfully used to measure the gas permeation flow rate ranging from 1 × 10 −5 to 1 × 10 −1 cm 3 (STP) s −1 , which indicates the broad applicability and reproducibility of the data suggesting the reliability of the designed apparatus. Permeation flow rates of binary mixtures of CO 2 /CH 4 through the defect-free membranes were compared with the numerical estimations to validate the measured transport properties.