Exploring the Impact of Active Site Structure on the Conversion of Methane to Methanol in Cu‐Exchanged Zeolites

• Published in: Angewandte Chemie 2024-06, Vol.136 (23), p.n/a
• Main Authors: Göltl, Florian, Bhandari, Saurabh, Lebrón‐Rodríguez, Edgard A., Gold, Jake I., Hutton, Daniel J., Zones, Stacey I., Hermans, Ive, Dumesic, James A., Mavrikakis, Manos
• Format: Article
• Language: English
• Subjects: C-H activation; Catalysts; Catalytic converters; Clusters; Cu-exchanged zeolites; Dimers; First principles; heterogeneous catlysis; Hydroxyl groups; Metal clusters; Methane; Methane to methanol; Methanol; Nitrous oxide; Oxidation; Phase diagrams; Stoichiometry; Transition metals; Zeolites
• ISSN: 0044-8249; 1521-3757
• DOI: 10.1002/ange.202403179

In the past, Cu‐oxo or ‐hydroxy clusters hosted in zeolites have been suggested to enable the selective conversion of methane to methanol, but the impact of the active site's stoichiometry and structure on methanol production is still poorly understood. Herein, we apply theoretical modeling in conjunction with experiments to study the impact of these two factors on partial methane oxidation in the Cu‐exchanged zeolite SSZ‐13. Phase diagrams developed from first‐principles suggest that Cu‐hydroxy or Cu‐oxo dimers are stabilized when O2 or N2O are used to activate the catalyst, respectively. We confirm these predictions experimentally and determine that in a stepwise conversion process, Cu‐oxo dimers can convert twice as much methane to methanol compared to Cu‐hydroxyl dimers. Our theoretical models rationalize how Cu‐di‐oxo dimers can convert up to two methane molecules to methanol, while Cu‐di‐hydroxyl dimers can convert only one methane molecule to methanol per catalytic cycle. These findings imply that in Cu clusters, at least one oxo group or two hydroxyl groups are needed to convert one methane molecule to methanol per cycle. This simple structure–activity relationship allows to intuitively understand the potential of small oxygenated or hydroxylated transition metal clusters to convert methane to methanol. We modify activation conditions to stabilize different Cu‐oxo and Cu‐hydroxyl dimers in the zeolite SSZ‐13. Subsequently we combine theory and experiment to investigate how the Cu site structure impacts the conversion of methane to methanol. Our results indicate that site stoichiometry controls methanol production in a stepwise conversion process.