Augmented energy storage and electrocatalytic performance via iron metal–organic framework infused with reduced graphene oxide/graphene quantum dots

• Published in: Applied physics. A, Materials science & processing Materials science & processing, 2024-06, Vol.130 (6), Article 443
• Main Authors: Zaka, Asma, Iqbal, Muhammad Waqas, Almutairi, Badriah S., Alrobei, Hussein, Ansar, Mohd Zahid
• Format: Article
• Language: English
• Subjects: Asymmetry; Characterization and Evaluation of Materials; Condensed Matter Physics; Energy storage; Graphene; Hydrogen evolution; Iron; Machines; Manufacturing; Metal-organic frameworks; Nanocomposites; Nanomaterials; Nanotechnology; Optical and Electronic Materials; Oxygen evolution reactions; Photoelectrons; Physics; Physics and Astronomy; Pore size; Processes; Quantum dots; Storage capacity; Structural stability; Surfaces and Interfaces; Thin Films; X ray photoelectron spectroscopy
• ISSN: 0947-8396; 1432-0630
• DOI: 10.1007/s00339-024-07562-z

A supercapattery is an advanced energy storage device with superior power and energy density compared to traditional supercapacitors and batteries. A facial and single-step hydrothermal method was adopted to synthesize the rGO/GQDs doped Fe-MOF nano-composites. The incorporation of the dopants into the host material was to improve the energy storage capacity and improve cyclic stability. The structural, morphological, and compositional analyses were conducted by employing X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Additionally, Brunauer–Emmett–Teller (BET) measurements were used to calculate the nanomaterial's surface area and pore size. Dunn’s model was used to demonstrate the contributions of the capacitive and diffusive components of the asymmetric energy storage structure. Fe-MOF/rGO/GQDs have a higher specific capacity (1876 C/g) than pure Fe-MOF (705 C/g) at 1.0 A/g current density. The Fe-MOF/rGO/GQDs supercapattery retained 95% of its capacity after 5000 charging and discharging cycles to test the asymmetric device durability. The power and energy densities have been determined to be 1160 W/kg and 57 Wh/kg, respectively. Fe-MOF showed excellent electrocatalytic activity in the hydrogen evolution process (HER) with a declined Tafel slope of 47.27 mV/dec. The Fe-MOF/rGO/GQDs electrode exhibits the lowest overpotential of 278 mV at 10 mA cm −2 with a Tafel slope of roughly 49.2 mV dec −1 in its function as an oxygen evolution reaction (OER) catalyst. This research work provides a basis for improving the efficiency of energy storage technologies.