Carbon nanofiber-wrapped core–shell MoO3 nanorod composite material for lithium-ion battery anodes

• Published in: Ionics 2024, Vol.30 (8), p.4497-4507
• Main Authors: Tang, Yi, Yang, Kejia, Chen, Han, Liu, Mingjun, Zhu, Bocan, Zhou, Zhitong, Liang, Guangyan, Yue, Chenxi, Chen, Jian
• Format: Article
• Language: English
• Subjects: Anodes; Carbon; Carbon fibers; Chemistry; Chemistry and Materials Science; Composite materials; Condensed Matter Physics; Diffusion rate; Dimensional analysis; Electrochemistry; Electrode materials; Electron transport; Energy Storage; Lithium; Lithium-ion batteries; Low currents; Membranes; Molybdenum trioxide; Nanofibers; Nanorods; Optical and Electronic Materials; Renewable and Green Energy
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-024-05591-5

In our pursuit of high-performance lithium-ion battery (LIB) anodes, we developed a hybrid electrospun membrane consisting of MoO 3 nanorods (MoO 3 NRs) integrated with carbon nanofibers (CNFs), termed MoO 3 @CNFs. Serving as an anode, this membrane boasts several advantages. Firstly, it capitalizes on the novel structure of MoO 3 @CNFs, enabling rapid ion/electron transport pathways. Secondly, due to the carbon skeleton, MoO 3 is protected from coming into direct contact with the electrolyte. Thirdly, the consistent internal structure of MoO 3 @CNFs enhances conductivity. Experimental findings reveal that the anode with a relatively low MoO 3 content, specifically 33%MoO 3 @CNFs (comprising 33%MoO 3 NRs), achieves a reversible specific capacity of 657 mAh g −1 after 140 cycles at a low current density of 0.2 A g −1 , demonstrating superior high-rate electrochemical kinetics and extended cycling life. Kinetic analysis indicates contributions from surface capacitance processes and diffusion-controlled insertion. Our approach not only facilitates the acquisition of various one-dimensional (1D) nanostructure composites but also propels novel research in ultrafast rechargeable lithium-ion battery electrode materials.