In‐situ preparation and performance of cellulose nanocrystals grafted with polyamide 6 composites

• Published in: Polymer composites 2024-09, Vol.45 (13), p.12187-12198
• Main Authors: Tao, Anmin, Shi, Hao, Gong, Mengqing, Liu, Mengting, Kan, Ze
• Format: Article
• Language: English
• Subjects: Caprolactam; Cellulose; cellulose nanocrystals; Glass transition temperature; Grafting; Heat resistance; Hydroxyl groups; in‐situ polymerization; Isocyanates; Melt blending; Nanocomposites; Nanocrystals; Nylon; Particulate composites; polyamide 6; Polyamide resins; Polymerization; reinforcement; Ring opening polymerization; Tensile strength; Thermal resistance; Thermodynamic properties; Toluene; Toluene diisocyanates
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.28629

Nylon nanocomposites were prepared by in‐situ ring‐opening polymerization to overcome the problem of poor properties due to the uneven dispersion of the nanoparticles by the traditional melt blending. This high‐performance polyamide 6 (PA6) nanocomposites with high dispersion and strong interface was prepared by grafting PA6 onto the surface of cellulose nanocrystals (CNC). The micromorphology, mechanical, crystalline and thermal properties of the composites were also investigated. Firstly, the hydroxyl group on the surface of CNC reacted with the para isocyanate of toluene diisocyanate (TDI), and the remaining ortho isocyanate was blocked by caprolactam to prepare CNC grafted with caprolactam (CNC‐g‐CL). Then CNC‐g‐CL was used as an activator to prepare cellulose nanocrystal grafted with polyamide 6 (CNC‐g‐PA6) composites by the ring‐opening polymerization of caprolactam on the CNC. The effects of different reaction temperatures, solvent amounts and molar ratios on the grafting rate of CNC‐g‐CL were investigated. The results showed that the highest grafting rate of CNC‐g‐CL with 66.7% was achieved at a reaction temperature of 45°C, 0.1 g/mL CNC in toluene, and a molar ratio of 6 for TDI/CNC. Further, different CNC‐g‐PA6 composites prepared from different CNC content and activator content were explored. For CNC‐g‐PA6 composites, CNC was uniformly dispersed in the PA6 matrix and had a good compatibility with the matrix. CNC exhibited significant reinforcement in the composites with a tensile strength of up to 108 MPa. In addition, the glass transition temperature of CNC‐g‐PA6 was increased to 92°C, which significantly improved the heat resistance of the new composites. Highlights Effects of reaction condition of CNC and TDI on DSTDI and DSCL were studied. Effects of CNC and activator content on CNC‐g‐PA6 properties were studied. CNC is uniformly dispersed in PA6 with average particle size less than 1 micron. The nylon matrix was significantly strengthened by the addition of CNC. The addition of CNC significantly improved the heat resistance of the composites. Overview of the preparation and property improvement of the CNC‐g‐PA6 composites.