Effects of Ligand vs. Linker on Phase Behavior and Mechanical Properties of Nanoparticle Gels

Nanoparticle gels have attracted considerable attention due to their highly tunable properties. One strategy for producing nanoparticle gels involves utilizing strong local attractions between polymeric molecules, such as DNA hybridization or dynamic covalent chemistry, to form percolated nanopartic...

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Bibliographic Details
Published in:arXiv.org 2024-10
Main Authors: Chen, Qizan, Dinesh Sundaravadivelu Devarajan, Nikoubashman, Arash, Howard, Michael P, Mittal, Jeetain
Format: Article
Language:English
Subjects:
Assemblies
Bend strength
Gels
Ligands
Mechanical properties
Nanoparticles
Phase separation
Stiffness
Tensile strength
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Summary:Nanoparticle gels have attracted considerable attention due to their highly tunable properties. One strategy for producing nanoparticle gels involves utilizing strong local attractions between polymeric molecules, such as DNA hybridization or dynamic covalent chemistry, to form percolated nanoparticle networks. These molecules can be used in two distinct roles: as ``ligands'' with one end grafted to a nanoparticle or as ``linkers'' with both ends free. Here, we explore how these roles shape the phase behavior and mechanical properties of gel-like nanoparticle assemblies using coarse-grained simulations. We systematically vary the interaction strength and bending stiffness of both ligands and linkers. We find that phase separation can be limited to low nanoparticle volume fractions by making the ligands rigid, consistent with previous studies on linked nanoparticle gels. At fixed interaction strength and volume fraction, both ligand- and linker-mediated nanoparticle assemblies show similar mechanical responses to variations in bending stiffness. However, a comparison between the two association schemes reveals that the linked nanoparticles form rigid percolated networks that are less stretchable than the ligand-grafted gels, despite exhibiting similar tensile strength. We attribute these differences between ligands and linkers to the distinct structural arrangement of nanoparticles. Our findings highlight the potential to utilize different association schemes to tune specific mechanical properties.
ISSN:2331-8422