Concept of Utilizing Ionic Liquids for the Co‐Electroreduction of Carbon Dioxide and Nitrogen‐Containing Compounds

• Published in: ChemCatChem 2024-11, Vol.16 (21), p.n/a
• Main Authors: Dongare, Saudagar, Coskun, Oguz Kagan, Gurkan, Burcu
• Format: Article
• Language: English
• Subjects: Aqueous electrolytes; Carbon dioxide; Chemical bonds; Chemical reactions; Electrocatalytic C−N coupling; Electrodes; Electrolysis; Electrolytes; Environmental chemistry; Hydrogen evolution reactions; Ionic liquid; Ionic liquids; Nitrogen dioxide; Pollution sources; Reaction intermediates; Urea
• ISSN: 1867-3880; 1867-3899
• DOI: 10.1002/cctc.202400966

Formation of C−N bonds through the electrochemical utilization of CO2 and nitrogen containing compounds (N‐compounds) is appealing for the purpose of converting waste and readily available sources or pollutants into value added chemicals at ambient conditions. Existing research predominantly explores these electrochemical reactions independently, often in aqueous electrolytes, leading to challenges associated with competitive hydrogen evolution reaction (HER), low product selectivity, and yield. Functional electrolytes such as those containing ionic liquids (ILs) present selective solubility to the solute reactants and present unique interactions with the electrode surface that can suppress the undesired side reactions such as HER while simultaneously co‐catalyzing the conversion of CO2 and N‐compounds such as N2, NO, NO2, and NO3. In this concept paper, we discuss how the microenvironment enabled by ILs can be leveraged to stabilize reaction intermediates at the electrode‐electrolyte interface, thereby promoting C−N bond formation on an active electrode surface at reduced overpotential, with the case study of CO2 and N‐compounds co‐catalysis to generate urea. Formation of C−N bonds through co‐electrolysis of CO2 and nitrogen‐containing compounds is a promising method for converting waste and readily available sources into valuable products such as urea – a nitrogen fertilizer. This paper presents the concept of utilizing ionic liquids (ILs) as electrolytes to leverage IL‐enabled microenvironments to stabilize reaction intermediates at the electrode‐electrolyte interface, thus promoting efficient C−N bond formation at reduced overpotentials.