(BO)2-doped tetrathia[7]helicenes: synthesis and property-change induced by “BO bond inversion”

Helical distortion of polyaromatic hydrocarbons gives rise to a special class of π-conjugated systems, namely helicenes. Owing to their configurational stability and easily tunable optoelectronic properties (via heteroatom-doping), helicenes have recently come to the fore as building blocks for appl...

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Published in:Organic chemistry frontiers an international journal of organic chemistry 2025-01, Vol.12 (3), p.725-735
Main Authors: Menduti, Luigi, Baldoli, Clara, Manetto, Simone, Villani, Claudio, Penconi, Marta, Grecchi, Sara, Arnaboldi, Serena, Mazzeo, Giuseppe, Longhi, Giovanna, Bolte, Michael, Virovets, Alexander, Hans-Wolfram Lerner, Wagner, Matthias, Licandro, Emanuela
Format: Article
Language:English
Subjects:
Benzene
Boron
Circular polarization
Doping
Doppler effect
Enantiomers
Energy gap
Low temperature
Optoelectronics
Phosphorescence
Polycyclic aromatic hydrocarbons
Racemization
Red shift
Rigidity
Synthesis
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