Rhodium‐Catalyzed Oxidative CH o‐Arylation of s‐Aryltetrazines with Aryl Boronic Acids: One‐Step Selective Access to T‐Shaped and Z‐Shaped Polyaromatics

The N‐directed rhodium‐catalyzed CH bond arylation of s‐aryltetrazine is reported using arylboronic acids as coupling partners. Convenient synthetic conditions are identified that avoid the 1,4‐azaphilic addition of the organometallic reagents on the tetrazine core, that may occur with organometall...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2025-09, Vol.367 (18), p.n/a
Main Authors: Abidi, Oumaima, Divoux, Gaëlle, Gelin, Loris, Cattey, Hélène, Fleurat‐Lessard, Paul, Hierso, Jean‐Cyrille, Roger, Julien
Format: Article
Language:English
Subjects:
Aromatic compounds
boronic acids
Chemical Sciences
Coupling
Cuprates
CH arylation
Nucleophiles
oxidative coupling
polyaromatics
Reagents
Rhodium
s‐tetrazine
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