Experimental demonstration of mass-filtered, time-dilated, time-of-flight mass spectrometry

• Published in: Surface and interface analysis 2011-01, Vol.43 (1-2), p.525-528
• Main Authors: Demoranville, L. T., Grabowski, K. S., Knies, D. L., Cetina, C.
• Format: Article
• Language: English
• Subjects: Accelerator Mass Spectrometry; Accelerators; Atomic, molecular, and ion beam impact and interactions with surfaces; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Dilation; duty cycle; Electron and ion emission by liquids and solids; impact phenomena; Electronics; Exact sciences and technology; Filtering; Filtration; Impact phenomena (including electron spectra and sputtering); mass spectrometer design; Mass spectrometers; Physics; Pretzels; Secondary Ion Mass Spectrometry; time-of-flight; Trace elements
• ISSN: 0142-2421; 1096-9918; 1096-9918
• DOI: 10.1002/sia.3524

The Trace Element Accelerator Mass Spectrometer (TEAMS) at the Naval Research Lab (NRL) offers a unique opportunity to develop a new type of time‐of‐flight Secondary Ion Mass Spectrometer (TOF‐SIMS). This opportunity derives from use of a Pretzel magnet as a recombinator and mass filter in the injector part to the accelerator. Mass filtering prior to time‐of‐flight analysis removes extraneous species, thereby reducing background for trace element analysis, and shortens the analysis time for a single‐beam pulse, thereby improving the duty cycle. Using this approach, it is possible to obtain expanded portions of a few narrow segments of the entire time‐of‐flight spectrum created by a single‐beam pulse. Additionally, a longer flight path with higher ion momenta in the Pretzel magnet introduces time dilation, thereby improving resolution. This type of TOF system is well suited for precise trace element abundance measurements, for example, the simultaneous measurement of fissionable nuclear material and selected fission fragments. Computer simulations and first test results led to recent modifications to electronics which have refined the system. These modifications resulted in the capability to produce a range of beam trigger widths and dwell times, while at the same time refining the peak shape. These capabilities allowed for the demonstration of mass filtering, interleaving and time dilation. While the NRL‐TEAMS system is not designed for TOF work, these results provide a demonstration of the capabilities of a future instrument. Copyright © 2010 John Wiley & Sons, Ltd.