Applying infrared thermography as a quality-control tool for the rapid detection of polymer-electrolyte-membrane-fuel-cell catalyst-layer-thickness variations

• Published in: Journal of power sources 2012-08, Vol.211, p.4-11
• Main Authors: Aieta, Niccolo V., Das, Prodip K., Perdue, Andrew, Bender, Guido, Herring, Andrew M., Weber, Adam Z., Ulsh, Michael J.
• Format: Article
• Language: English
• Subjects: Applied sciences; Catalyst layer; Catalysts; Defects; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cell; Fuel cells; Infrared; Infrared thermography; Manufacturing; Materials; Mathematical analysis; Mathematical models; PEMFC; Production methods; Quality control; Thermography
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2012.02.030

As fuel cells become more prominent, new manufacturing and production methods are needed to enable increased volumes with high quality. One necessary component of this industrial growth will be the accurate measurement of the variability of a wide range of material properties during the manufacturing process. In this study, a method to detect defects in fuel cell catalyst layers is investigated through experiment and mathematical simulation. The method uses infrared thermography and direct-current electronic-excitation methods to detect variations in platinum-containing catalyst-layer thickness with high spatial and temporal resolution. Data analysis, operating-condition impacts, and detection limits are explored, showing the measurement of defects on the millimeter length scale. Overall, the experimental and modeling results demonstrate great potential of this technique as a nondestructive method to measure defects that is amenable to use on roll-to-roll manufacturing lines. ► The infrared thermography technique described can monitor small (at least as small as 0.01-cm2) variations in catalyst layer thickness. ► The technique has temporal resolutions of 1s or less. ► The technique is noncontact and nondestructive, and thus can be used for in-line inspection.