Natural radionuclides and metals intake into soya, corn and lettuce grown on soil amended with phosphogypsum

• Published in: International journal of environmental analytical chemistry 2012-12, Vol.92 (14), p.1574-1586
• Main Authors: Mazzilli, Barbara P, Saueia, Cátia H.R, Jacomino, Vanusa M.F, Mello, Jaime W.V
• Format: Article
• Language: English
• Subjects: Analytical chemistry; arsenic; barium; cadmium; chromium; clay soils; cobalt; copper; corn; Crops; fertilizer industry; iron; lead; Lettuce; metals; natural radionuclides; nickel; Phosphatic fertilizers; phosphogypsum; phosphorus fertilizers; radionuclides; rocks; sandy soils; soil amendments; soybeans; Trace elements; transfer-factor; zinc
• ISSN: 1029-0397; 0306-7319; 1029-0397
• DOI: 10.1080/03067319.2010.549339

Phosphogypsum is a by-product of the phosphate fertilizer industry. It is produced by precipitation during wet process of phosphate rocks, thus posing serious problems with its utilization and safe disposal. In Brazil, three main industries are responsible for the production and storage of about 5.5 × 10⁶ tons per year. Phosphogypsum may contain trace metals and radionuclides of U and Th series. Since, in Brazil, phosphogypsum has been used for many years as soil amendment, it is important to know its availability in the environment. The main objective of this study is to evaluate the radionuclides and metals transfer in the soil-to-plant system. To accomplish this task an experiment was carried out in a green house, where two major crop groups (soya bean and corn) and leafy vegetables (lettuce) were grown in two types of soil (clay and sandy) amended with phosphogypsum. The transfer-factors were evaluated for the metals (As, Cd, Cu, Ni and Pb, Ba, Co, Cr, Fe, Zn and REE) and for the radionuclides U, Th, ²²⁶Ra, ²²⁸Ra, ²¹⁰Pb and ²¹⁰Po. The addition of PG to the two soils studied, did not significantly alter the TFs values for all the elements studied.