Direct Lactonization of 2‑Arylacetic Acids through Pd(II)-Catalyzed C–H Activation/C–O Formation

Palladium-catalyzed direct lactonization of 2-arylacetic acids through a reaction sequence that includes C–H activation/C–O formation is reported. This method provides a concise and efficient pathway to synthesize fully functionalized benzofuranone derivatives, which are highly relevant to bioactive...

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Published in:Organic letters 2013-02, Vol.15 (3), p.690-693
Main Authors: Yang, Mingyu, Jiang, Xingyu, Shi, Wen-Juan, Zhu, Qi-Lei, Shi, Zhang-Jie
Format: Article
Language:English
Subjects:
Acetates - chemistry
Benzofurans - chemical synthesis
Benzofurans - chemistry
Carboxylic Acids - chemistry
Catalysis
Molecular Structure
Palladium - chemistry
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cited_by cdi_FETCH-LOGICAL-a381t-b0ad24668fa8ade2399a774d4650d318151b6fc9bedce4c6d43d3af70a801b263
cites cdi_FETCH-LOGICAL-a381t-b0ad24668fa8ade2399a774d4650d318151b6fc9bedce4c6d43d3af70a801b263
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container_title Organic letters
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creator Yang, Mingyu
Jiang, Xingyu
Shi, Wen-Juan
Zhu, Qi-Lei
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description Palladium-catalyzed direct lactonization of 2-arylacetic acids through a reaction sequence that includes C–H activation/C–O formation is reported. This method provides a concise and efficient pathway to synthesize fully functionalized benzofuranone derivatives, which are highly relevant to bioactive natural and synthetic products.
doi_str_mv 10.1021/ol303569b
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Acetates - chemistry
Benzofurans - chemical synthesis
Benzofurans - chemistry
Carboxylic Acids - chemistry
Catalysis
Molecular Structure
Palladium - chemistry
title Direct Lactonization of 2‑Arylacetic Acids through Pd(II)-Catalyzed C–H Activation/C–O Formation
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