MCM-48 modified magnetic mesoporous nanocomposite as an attractive adsorbent for the removal of sulfamethazine from water

• Published in: Water research (Oxford) 2013-08, Vol.47 (12), p.4107-4114
• Main Authors: Qiang, Zhimin, Bao, Xiaolei, Ben, Weiwei
• Format: Article
• Language: English
• Subjects: adsorbents; Adsorption; aniline; Anions; heat production; humic acids; Humic Substances - analysis; Hydrogen Bonding; Hydrogen-Ion Concentration; Magnetic mesoporous nanocomposite; Magnetic Phenomena; MCM-48; Models, Chemical; nanocomposites; Nanocomposites - chemistry; Nanocomposites - ultrastructure; nitrogen; Porosity; Powders; Solutions; sorption isotherms; Sulfamethazine; Sulfamethazine - chemistry; Sulfamethazine - isolation & purification; Temperature; Water; Water Pollutants, Chemical - isolation & purification; X-Ray Diffraction
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/j.watres.2012.10.039

A novel magnetic mesoporous nanocomposite FeM48 was synthesized and applied to remove sulfamethazine (SMN) from water. The adsorption kinetics could be expressed by the pseudo-second-order model, where external and interfacial diffusions tended to be the rate-limiting step. The adsorption isotherms at varied temperatures were fitted well with Freundlich model, and thermodynamic analysis revealed that SMN adsorption on FeM48 was a spontaneous exothermic process. Solution pH exhibited a remarkable impact on the adsorption process and the maximum adsorbed concentration was obtained at pH 6.3. The effect of co-existing anions and humic acid demonstrated that SMN could be adsorbed selectively by FeM48. Hydrogen bonding between the nitrogen of the aniline, sulfinol or pyrimidine group of SMN and the surface hydroxyl group of FeM48 was the major driving force for adsorption. In addition, the π–π electron-donor–acceptor interaction between SMN (π-electron–acceptor) and MCM-48 (π-electron–donor) also promoted the adsorption process. [Display omitted] ► Magnetic mesoporous nanocomposite FeM48 was synthesized and characterized. ► FeM48 removed SMN from water effectively and selectively around neutral pH. ► The adsorption of SMN on FeM48 was a spontaneous exothermic process. ► Hydrogen bonding was the major driving force for SMN adsorption on FeM48. ► π–π electron–donor–acceptor interaction promoted the adsorption process.