The structure of novel polyurethanes containing synthetic poly[(R,S)-3-hydroxybutyrate]

• Published in: Journal of applied polymer science 2012-09, Vol.125 (6), p.4285-4291
• Main Authors: Brzeska, Joanna, Dacko, Piotr, Gębarowska, Katarzyna, Janik, Helena, Kaczmarczyk, Bożena, Kasperczyk, Janusz, Kowalczuk, Marek, Rutkowska, Maria
• Format: Article
• Language: English
• Subjects: Applied sciences; Band spectra; Exact sciences and technology; Hydrogen bonds; Materials science; Organic polymers; Physicochemistry of polymers; Polycondensation; Polymerization; Polymers; Polyurethane resins; polyurethanes; Preparation, kinetics, thermodynamics, mechanism and catalysts; Reproduction; Segments; Spectral lines; structure; synthetic atactic polyhydroxybutyrate; Urethanes
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.36599

The aim of this study was to estimate the structure of new polyurethanes with the potential to be used in medicine. Atactic poly[(R,S)‐3‐hydroxybutyrate], obtained via a ring‐opening polymerization, and polycaprolactonediol or polyoxytetramethylenediol were used to built the soft segments. 4,4′‐methylene dicyclohexyl diisocyanate and 1,4‐butanediol were the components to form hard segments. At FTIR spectra of obtained polyurethanes the bands attributed to NCO groups completely disappeared, similarly as these of OH groups and the new band characteristic for stretching vibrations of bonded urethane NH groups appeared. Polyurethanes with low‐molecular weight were obtained. The observation of FTIR and 1H‐NMR spectra had been suggested that NH groups form two types of hydrogen bonds: with CO urethane (possibly with ester group) and ether groups. An addition of poly[(R,S)‐3‐hydroxybutyrate] caused the slight increase in number of urethane–urethane hydrogen bonds. For some of polyurethanes (based on polyoxytetramethylenediol) the allophanate structures were obtained. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012