Temperature-controlled selectivity in oxidation of 1-octene by using aqueous hydrogen peroxide in phase-boundary catalytic system

• Published in: Applied catalysis. A, General General, 2013-06, Vol.460-461, p.21-25
• Main Authors: Yuan, Lai Sin, Razali, Rasidah, Efendi, Jon, Buang, Nor Aziah, Nur, Hadi
• Format: Article
• Language: English
• Subjects: Alkylsilylated-Ti(IV) salicylaldimine complex; Attachment; Catalysis; Catalysts; Chemistry; Exact sciences and technology; General and physical chemistry; Hydrogen peroxide; Immiscible liquid–liquid; Oxidation; Phase boundaries; Phase-boundary catalysis; Precursors; Selectivity; Temperature-controlled selectivity; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2013.04.016

•Alkylsilylated-titanium(IV) salicylaldimine complex as phase-boundary catalyst.•Temperature-controlled selectivity in oxidation of 1-octene by aqueous H2O2.•High selectivity in oxidation of 1-octene by aqueous H2O2 at low temperature.•Partitioning of catalyst in immiscible liquid–liquid phase boundary.•Effect of consolute boundary of the liquid–liquid phase to catalytic selectivity. Temperature-controlled selectivity in oxidation of 1-octene by using aqueous hydrogen peroxide in phase-boundary catalytic system was demonstrated by using alkylsilylated-Ti(IV) salicylaldimine complex at a series of temperature (25–90°C). The catalyst was synthesized by titanium(IV) sulfate solution, salicylaldehyde, and 3-aminopropyltrimethoxysilane as the precursors and followed by the attachment of octadecyltrimethoxysilane. It was found that the reaction system resulted in high selectivity at low temperature. One suggests that the high selectivity in the oxidation of 1-octene by aqueous hydrogen peroxide was related to partitioning of alkylsilylated-titanium(IV) salicylaldimine complex in immiscible liquid–liquid phase boundary which is temperature dependent.