Self-Assembly and (Hydro)gelation Triggered by Cooperative π-π and Unconventional CH⋅⋅⋅X Hydrogen Bonding Interactions

Weak CH⋅⋅⋅X hydrogen bonds are important stabilizing forces in crystal engineering and anion recognition in solution. In contrast, their quantitative influence on the stabilization of supramolecular polymers or gels has thus far remained unexplored. Herein, we report an oligophenyleneethynylene (OP...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2014-01, Vol.53 (3), p.700-705
Main Authors: Rest, Christina, Mayoral, María José, Fucke, Katharina, Schellheimer, Jennifer, Stepanenko, Vladimir, Fernández, Gustavo
Format: Article
Language:English
Subjects:
Alkynes - chemistry
amphiphiles
Carbon - chemistry
Chlorine - chemistry
cooperativity
Coordination Complexes - chemistry
Ethers - chemistry
Gels - chemistry
Hydrogen - chemistry
Hydrogen Bonding
Oxygen - chemistry
Platinum - chemistry
Quantum Theory
supramolecular polymerization
Temperature
Water - chemistry
X-H hydrogen bonds
π-conjugated systems
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