Pyridine-Mediated S -Vinylation of the Mercapto Group in Heterocyclic Compounds

A good yield in the stereospecific synthesis of S-vinylated mercapto groups in heterocyclic compounds is described involving the reaction of acetylenic esters and 2-mercapto-1-methylimidazole or 5-mercapto-1-methyltetrazole in the presence of pyridine. This one-pot method is simple and effective und...

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Bibliographic Details
Published in:Journal of chemical research 2013-09, Vol.37 (9), p.523-525
Main Authors: Asgharian-Sheykhi, Fahimeh, Hassanabadi, Alireza, Akhgar, Mohammad Reza, Karbalaei-Harofteh, Mina, Khajehpour, Ehsan
Format: Article
Language:English
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Esters
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Summary:A good yield in the stereospecific synthesis of S-vinylated mercapto groups in heterocyclic compounds is described involving the reaction of acetylenic esters and 2-mercapto-1-methylimidazole or 5-mercapto-1-methyltetrazole in the presence of pyridine. This one-pot method is simple and effective under mild conditions.
ISSN:1747-5198
2047-6507
DOI:10.3184/174751913X13736131855630