Synthesis, magnetic and Mössbauer spectroscopic studies of Cr doped lithium ferrite nanoparticles

• Published in: Journal of alloys and compounds 2014-04, Vol.591, p.174-180
• Main Authors: Srivastava, Manish, Layek, Samar, Singh, Jay, Das, Ashok Kumar, Verma, H.C., Ojha, Animesh K., Kim, Nam Hoon, Lee, Joong Hee
• Format: Article
• Language: English
• Subjects: Cations; Chromium; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Crystallites; Exact sciences and technology; Lithium ferrite; Magnetic properties; Magnetic properties and materials; Magnetic properties of nanostructures; Magnetic resonances and relaxations in condensed matter, mössbauer effect; Mossbauer effect; Mössbauer effect; other γ-ray spectroscopy; Mössbauer spectroscopy; Nanoparticles; Physics; Spectroscopic analysis; Spectroscopy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2013.12.180

•Chromium doped lithium ferrite nanoparticles have been synthesized at different pH.•Distributions of cations over the tetrahedral/octahedral voids have been adjusted.•Octahedral site is more preferable for Fe3+ at higher pH.•Magnetic properties of the samples have been tuned by pH variation. Lithium-based ferrites are promising and potential magnetic materials for microwave applications. They possess a spinel (AB2O4) type crystal structure, where the distributions of metal cations over the tetrahedral (A) and octahedral (B) voids play a crucial role for exhibiting different physical properties. Among various parameter of synthesis, pH is an important factor that influences the cation distribution over A and B voids, overall growth of the nanoparticles and different physical properties. In the present work single phase Cr substituted lithium ferrite nanoparticles have been synthesized by the sol–gel method at different pH. The phase identification and crystallite size have been probed by X-ray diffraction studies. The crystallite size changes by 44.2–48.8nm upon varying the pH from 3.5 to 11.5. In order to investigate the cations distribution at A/B sites, Mössbauer spectroscopic measurements were done. The values of magnetic hyperfine field obtained from the Mössbauer data for the A and B sites are ≈49.5T and 51T, respectively. Moreover, it is observed that the area ratio of B site to A site increases with increasing the pH. This observation further suggests that the B site is more preferable for Fe3+ cations at higher pH than the A site. The magnetic parameter such as saturation magnetization (Ms), remanent magnetization (Mr), coercive field (HC) and squareness (S) are determined by vibrating sample magnetometer (VSM) measurements, which show a consistent increase with increasing pH. The reason for the variation in magnetic properties has been explained on the basis of increased Fe3+ cation occupancies at the B site and size effect, which is well supported by Mössbauer spectroscopic and XRD studies.