Salinity Selection for a Low Salinity Water-Low Salinity Surfactant Process

A laboratory selection of salinity for a low salinity water-low salinity surfactant (LS-LSS) process is presented in this paper with systematical investigation on surfactant phase behavior, interfacial tension (IFT), and dynamic retention in porous media with IOS2024 and isoamyl alcohol (IAA) as sur...

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Bibliographic Details
Published in:Journal of dispersion science and technology 2014-04, Vol.35 (4), p.551-555
Main Authors: Sun, Limei, Spildo, Kristine, Djurhuus, Ketil, Skauge, Arne
Format: Article
Language:English
Subjects:
Boundaries
Chemistry
Colloidal state and disperse state
Dynamic tests
Dynamical systems
Dynamics
Exact sciences and technology
General and physical chemistry
Interfacial tension
optimal salinity
Optimization
phase behavior
Retention
Saline water
Salinity
Surfactants
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Summary:A laboratory selection of salinity for a low salinity water-low salinity surfactant (LS-LSS) process is presented in this paper with systematical investigation on surfactant phase behavior, interfacial tension (IFT), and dynamic retention in porous media with IOS2024 and isoamyl alcohol (IAA) as surfactant system. The results show that 0.4 wt% IOS2024 with 1 wt% IAA can provide ultra-low IFT of 10 −3 mN/m at around 3000-4000 mg/L total dissolved solids, but at that salinity range the surfactant retention is very high. The search for an optimum surfactant formulation has to consider solution properties and retention in addition to the low IFT. The salinity for a LS-LSS process should thus not be focused on either optimal salinity or ultra-low IFT, but instead the best choice could be a compromise between the properties in question. The three-phase region, where ultra-low IFT are found, is also associated with high retention values. However, we show that as salinity is increased from a two-phase region with oil solubilized in a water continuous microemulsion, there is a region close to the three-phase boundary which has potential. This region does not give ultra-low, but fairly low (10 −2 mN/m in this case) interfacial tensions, and also significantly lower retention.
ISSN:0193-2691
1532-2351
DOI:10.1080/01932691.2013.800456