Palladium supported on clays to catalytic deoxygenation of soybean fatty acids

• Published in: Applied clay science 2014-06, Vol.95, p.388-395
• Main Authors: Detoni, Chaline, Bertella, Francine, Souza, Mariana M.V.M., Pergher, Sibele B.C., Aranda, Donato A.G.
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts; Chemisorption; Clays; Deoxygenation; Earth sciences; Earth, ocean, space; Exact sciences and technology; Fatty acids; Hydrocarbons; i-Alkanes; Mineralogy; Palladium; Silicates; Soybeans
• ISSN: 0169-1317; 1872-9053
• DOI: 10.1016/j.clay.2014.04.026

This work aims at the soybean free fatty acid deoxygenation using palladium supported (1wt.%) on different clays as catalysts. The results presented a promising technology for the single-stage production of hydrocarbons in the diesel fuel range. Clays used as palladium support were a natural Brazilian Montmorillonite (BM), this same clay in its pillared form (PILCBM) and two commercial clays (K10 and KSF). Catalysts were characterized by N2 adsorption, X-ray diffraction (XRD), FTIR spectra of adsorbed pyridine, CO chemisorption and scanning electron microscopy (SEM). Reactions were carried out in batch mode, under different H2 pressures (10, 20, 30 and 40bar) at 300°C. Reactions performed using Pd/K10 as catalyst at 30bar of H2 presented interesting results: 74.5% conversion after 6h and selectivities to n- and i-alkanes equal to 69% and 29%, respectively. [Display omitted] •Pd/clays were used as catalysts to transform free fatty acids in hydrocarbons.•n- and i-alkanes were obtained as main products when Pd/K10 was used as catalyst.•Efficient method to obtain high quality fuel from renewable raw material•Pd/K10 shows high activity–selectivity to produce hydrocarbons in the diesel range.