Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis

The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.

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Published in:Organic letters 2015-03, Vol.17 (5), p.1328-1331
Main Authors: Lin, Cong, Li, Danyang, Wang, Binjie, Yao, Jinzhong, Zhang, Yuhong
Format: Article
Language:English
Subjects:
Alkenes - chemistry
Catalysis
Molecular Structure
Nickel - chemistry
Stereoisomerism
Sulfhydryl Compounds - chemistry
Sulfides - chemistry
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cited_by cdi_FETCH-LOGICAL-a411t-677f8d5e87a0c02b0ed111e3fadcb1c88b40f78f622b64e0b672d184355415823
cites cdi_FETCH-LOGICAL-a411t-677f8d5e87a0c02b0ed111e3fadcb1c88b40f78f622b64e0b672d184355415823
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creator Lin, Cong
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description The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.
doi_str_mv 10.1021/acs.orglett.5b00337
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subjects Alkenes - chemistry
Catalysis
Molecular Structure
Nickel - chemistry
Stereoisomerism
Sulfhydryl Compounds - chemistry
Sulfides - chemistry
title Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis
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