Mechanical and interfacial properties of wood and bio-based thermoplastic composite

• Published in: Composites science and technology 2012-09, Vol.72 (14), p.1733-1740
• Main Authors: Sliwa, Fabien, El Bounia, Nour-eddine, Charrier, Fatima, Marin, Gérard, Malet, Frédéric
• Format: Article
• Language: English
• Subjects: A. Polymer–matrix composites (PMCs); Applied sciences; B. Interface; B. Mechanical properties; Composites; D. Differential scanning calorimetry (DSC); D. Scanning electron microscopy (SEM); Differential scanning calorimetry; Dispersions; Exact sciences and technology; Fibers; Forms of application and semi-finished materials; Mechanical properties; Polymer industry, paints, wood; Scanning electron microscopy; Technology of polymers; Tensile tests; Thermoplastic elastomers; Wood
• ISSN: 0266-3538; 1879-1050
• DOI: 10.1016/j.compscitech.2012.07.002

The aim of this investigation was to study a new family of wood polymer composites with thermoplastic elastomer matrix (pebax® copolymers) instead of commonly used WPC matrices. These copolymers are polyether-b-amide thermoplastic elastomers which present an important elongation at break and a melting point below 200°C to prevent wood fibers degradation during processing. Moreover these polymers are synthesized from renewable resources and they present a hydrophilic character which allow them to interact with wood fibers. We have used two pebax® grade with different hardness and three types of wood fibers, so the influence of the matrix and wood fibers characteristics were evaluated. Composites were produced using a laboratory-size twin screw extruder to obtain composite pellets prior to injection moulding into tensile test samples. We have evaluated fibers/matrix interaction by differential scanning calorimetry (DSC), infrared spectroscopy (IRTF) and scanning electron microscopy (SEM). Then, the mechanical properties, through tensile test, were assessed. We also observed fibers dispersion into the matrix by tomography X. DSC, IRTF and SEM measurements confirmed the presence of strong interface interactions between polymer and wood. These interactions lead to good mechanical properties of the composites with a reinforcement effect of wood fibers due also to a good dispersion of fibers into the matrix without agglomerate.