Development of anti-icing materials by chemical tailoring of hydrophobic textured metallic surfaces

• Published in: Journal of colloid and interface science 2013-03, Vol.394, p.539-544
• Main Authors: Charpentier, Thibaut V.J., Neville, Anne, Millner, Paul, Hewson, Rob W., Morina, Ardian
• Format: Article
• Language: English
• Subjects: Anti-icing surfaces; Brushes; Charging; Chemistry; composite materials; cooling; electrolytes; Electrolytes - chemistry; Entropy; Exact sciences and technology; Freezing; General and physical chemistry; humans; Hydrophobic and Hydrophilic Interactions; Hydrophobic textured stainless-steel; hydrophobicity; ice; Ice - analysis; Ice formation; Models, Molecular; Nucleation; Polyelectrolytes brushes; stainless steel; Stainless Steel - chemistry; Stainless steels; Surface chemistry; Surface physical chemistry; Surface Properties; temperature
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2012.11.021

[Display omitted] ► Textured hydrophobic steel was achieved laser ablation process. ► Anionic polymer brushes were attached on textured surfaces. ► Dual hydrophobic negatively charged surfaces reduce greatly freezing temperature. ► Hydrophobic surfaces lower the population of nucleating agents available. ► Negatively charged surface reduce the ice entropy which lower freezing temperature. Ice on surfaces can have dramatic consequences for human activities. Over the last decades, the design of new materials with anti-icing properties has generated significant research efforts for the prevention of ice accretion. Here we investigate water freezing temperatures on untreated and negatively charged hydrophobic stainless steel surfaces and use these temperatures to evaluate icephobicity. Supercooled water microdroplets are deposited and undergo a slow controlled cooling until spontaneous freezing occurs. Textured hydrophobic stainless steel surfaces functionalized with anionic polyelectrolytes brushes display unexpectedly lower freezing temperatures, at least 7°C lower than polished untreated steel. On the basis of the entropy reduction of the crystalline phase near a charged solid surface, we used a modification of the classical heterogeneous nucleation theory to explain the observed freezing temperatures lessening. Our results could help the design of new composite materials that more efficiently prevent ice formation.