A novel chitosan/clay/magnetite composite for adsorption of Cu(II) and As(V)

► A composite composed of chitosan, nano-magnetite, and heulandite was prepared. ► Properties of the composite were characterized using various instrumentation. ► The composite was applied as an adsorbent for removal of Cu(II) and As(V). ► The optimal mass ratio of chitosan, nano-magnetite, and heul...

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Bibliographic Details
Published in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2012-08, Vol.200-202, p.654-662
Main Authors: Cho, Dong-Wan, Jeon, Byong-Hun, Chon, Chul-Min, Kim, Yongje, Schwartz, Franklin W., Lee, Eung-Seok, Song, Hocheol
Format: Article
Language:English
Subjects:
adsorbents
Adsorption
Applied sciences
Aqueous solutions
Arsenic
Chemical engineering
Chitosan
Clay
CLAYS
COMPOSITES
Copper
Crosslinking
Endothermic reactions
Exact sciences and technology
ions
MAGNETITE
MICROSTRUCTURES
Nanomaterials
Nanostructure
SOLUTIONS
Surface chemistry
Tripolyphosphate
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Summary:► A composite composed of chitosan, nano-magnetite, and heulandite was prepared. ► Properties of the composite were characterized using various instrumentation. ► The composite was applied as an adsorbent for removal of Cu(II) and As(V). ► The optimal mass ratio of chitosan, nano-magnetite, and heulandite was 1:1:2. ► We demonstrated potential utility of the material in environmental cleanup. A composite adsorbent was prepared by entrapping cross-linked chitosan and nano-magnetite (NMT) on heulandite (HE) surface to remove Cu(II) and As(V) in aqueous solution. The optimized mass ratio among chitosan, HE, and NMT was determined to be 1:1:2. Kinetics studies indicated the removal of both ions followed pseudo-second order kinetics, suggesting specific interaction with surface functional groups was the major route of the removal process. The composite gave the maximum equilibrium uptakes of Cu(II) and As(V) of 17.2 and 5.9mgg−1 in initial concentration ranges of 16–656 and 17–336mgL−1, respectively. The thermodynamic data showed that both adsorption processes were thermodynamically favorable, spontaneous, and endothermic nature. The adsorption capacity for Cu(II) increased continuously with an increase in initial solution pH (3–9), but adsorption of As(V) showed an opposite trend. The overall results demonstrated the potential utility of the composite for Cu(II) and As(V) removal from aqueous solutions.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2012.06.126