Sulfonamide-substituted iron phthalocyanine: design, solubility range, stability and oxidation of olefins

4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(ii) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stabil...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2014-12, Vol.43 (48), p.17916-17919
Main Authors: Işci, Umit, Caner, Celal, Zorlu, Yunus, Gürek, Ayşe Gül, Dumoulin, Fabienne, Ahsen, Vefa
Format: Article
Language:English
Subjects:
Benzaldehyde
Iron
Ketones
Olefins
Oxidation
Solubility
Stability
Styrenes
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Summary:4-tert-Butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(ii) phthalocyanine, taking into account several parameters crucial for the design of potential oxidation catalysts such as solubility and stability. The resulting phthalocyanine exhibits a remarkable stability under oxidative conditions. The main product of the oxidation of cyclohexene using H2O2 as the oxidant is the allylic ketone, 2-cyclohexen-1-one. Styrene oxidation led mainly to the formation of benzaldehyde.
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt02412e