Loading…

Peptidomimetic organocatalysts: efficient Michael addition of ketones onto nitroolefins with very low catalyst loading

The syntheses of two novel peptidomimetic triazole-based organocatalysts that work for the asymmetric conjugate addition of cyclohexanone to nitroolefins are described. The catalysts worked with very low loading (0.5 mol%) in the absence of any additives to provide high diastereo- and enantio-select...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances 2014-01, Vol.4 (57), p.30325-30331
Main Authors: Chandrasekhar, Srivari, Kumar, Chintakunta Praveen, Kumar, Togapur Pavan, Haribabu, Kothapalli, Jagadeesh, Bharatam, Lakshmi, Jerripothula K, Mainkar, Prathama S
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The syntheses of two novel peptidomimetic triazole-based organocatalysts that work for the asymmetric conjugate addition of cyclohexanone to nitroolefins are described. The catalysts worked with very low loading (0.5 mol%) in the absence of any additives to provide high diastereo- and enantio-selectivities.
ISSN:2046-2069
2046-2069
DOI:10.1039/c4ra04165h