Thermodynamic and Spectroscopic Identification of Guest Gas Enclathration in the Double Tetra-n-butylammonium Fluoride Semiclathrates

The precise nature and unique pattern of the double tetra-n-butylammonium fluoride (TBAF) semiclathrates with a guest gas (CH4 or CO2) was closely investigated through thermodynamic and spectroscopic analyses. The three-phase equilibria of semiclathrate (H), liquid water (LW), and vapor (V) for the...

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Bibliographic Details
Published in:The journal of physical chemistry. B 2012-08, Vol.116 (30), p.9075-9081
Main Authors: Lee, Seungmin, Lee, Youngjun, Park, Sungwon, Kim, Yunju, Lee, Ju Dong, Seo, Yongwon
Format: Article
Language:English
Subjects:
Cages
Carbon dioxide
chemical elements
Fluorides
Hydrates
methane
nuclear magnetic resonance spectroscopy
physical chemistry
spectral analysis
Spectroscopic analysis
thermal stability
Thermodynamics
Uptakes
vapors
Water
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