Facile synthesis of porous graphene as binder-free electrode for supercapacitor application

• Published in: Applied surface science 2016-03, Vol.366, p.46-52
• Main Authors: Luo, Guangsheng, Huang, Haifu, Lei, Chenglong, Cheng, Zhenzhi, Wu, Xiaoshan, Tang, Shaolong, Du, Youwei
• Format: Article
• Language: English
• Subjects: Capacitors; Electrodes; Foams; Graphene; Hydrothermal; Ni foam; Nickel; Polystyrene resins; Porous; Supercapacitor; Supercapacitors; Texture
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2016.01.015

•Our results provide a facile method to fabricate a binder-free porous rGO electrode for supercapacitors.•Polystyrene (PS) colloidal particles were used as spacers to prepare high-performance porous grapheme deposited directly on Ni foam substrate.•The specific capacitance of the rGO/NF electrode decreased by 7% after 2000 cycles and high rate capability of 53% capacitance retention at 100Ag−1. Here, porous grapheme oxide (GO) gel deposited on nickel foam was prepared by using polystyrene (PS) colloidal particles as spacers for use as electrodes in high rate supercapacitors, then reduced by Vitamin C aqueous solution in ambient condition. The PS particles were surrounded by reduced graphene oxide (rGO) sheets, forming crinkles and rough textures. When PS particles were selectively removed, rGO gel coated on the skeleton of Ni foam can formed an open porous structure, which prevents elf-aggregation and restacking of graphene sheets. The porous rGO-based supercapacitors exhibit excellent electrochemical performances such as a specific capacitance of 152Fg−1 at 1Ag−1, high rate capability of 53% capacitance retention upon a current increase to 100Ag−1 and good cycle stability, due to effective rapid and short pathways for ionic and electronic transport provided by the sub-micrometer structure of rGO gel and 3D interconnected network of Ni foam.