Sol–gel combustion synthesis, particle shape analysis and magnetic properties of hematite (α-Fe2O3) nanoparticles embedded in an amorphous silica matrix

• Published in: Applied surface science 2016-01, Vol.362, p.380-386
• Main Authors: Kopanja, Lazar, Milosevic, Irena, Panjan, Matjaz, Damnjanovic, Vesna, Tadic, Marin
• Format: Article
• Language: English
• Subjects: Amorphous silica; Combustion synthesis; Exchange; Hematite; Hematite (α-Fe2O3); Iron oxide; Magnetic properties; Magnetization; Nanoparticles; Nanostructure; Silicon dioxide; Superparamagnetism (SPION); Surface effects
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2015.11.238

•Hematite nanoparticles are synthesized by using sol–gel combustion synthesis method.•The SQUID measurements show blocking temperature TB=27K and superparamagnetism.•TEM measurements show spherical particles and narrow size distribution.•The sample did not exhibit the Morin transition.•The magnetic moment μp=195μB and diameter d=5nm were determined. We report the synthesis and magnetic properties of hematite/amorphous silica nanostructures. Raman spectroscopy showed the formation of a hematite phase. A transmission electron microscopy (TEM) revealed spherically shaped hematite nanoparticles, well-dispersed in an amorphous silica matrix. In order to quantitatively describe morphological properties of nanoparticles, we use the circularity of shapes as a measure of how circular a shape is. Diameters of about 5nm and a narrow size distribution of nanoparticles are observed. The obtained hematite nanoparticles exhibit superparamagnetic properties at room temperature (SPION). The sample does not display the Morin transition. The FC hysteresis loop at 5K has shown an exchange bias effect. These results have been compared to those previously reported for α-Fe2O3/SiO2 nanosystems in the literature. These comparisons reveal that the sol–gel combustion method yields hematite nanoparticles with a higher magnetization and magnetic moment. These data indicate the existence of an additional factor that contributes to magnetization. We suggest that the increased magnetization is due to an increased number of the surface spins caused by the breaking of large numbers of exchange bonds between surface atoms (disordered structure). This leads to an increase in the magnetic moment per a hematite nanoparticle and an exchange bias effect. We have concluded that the combustion-related part of this synthesis method enhances surface effects, i.e. it promotes the breaking of bonds and surface disordered layers, which results in these magnetic properties. Such interesting structural and magnetic properties of hematite might be important in future practical applications and fundamental research.