Amino-Functionalized Conjugated Polymer as an Efficient Electron Transport Layer for High-Performance Planar-Heterojunction Perovskite Solar Cells

• Published in: Advanced energy materials 2016-03, Vol.6 (5), p.np-n/a
• Main Authors: Sun, Chen, Wu, Zhihong, Yip, Hin-Lap, Zhang, Hua, Jiang, Xiao-Fang, Xue, Qifan, Hu, Zhicheng, Hu, Zhanhao, Shen, Yan, Wang, Mingkui, Huang, Fei, Cao, Yong
• Format: Article
• Language: English
• Subjects: Cathodes; Electron transport; electron transport layers; Energy conversion efficiency; Fullerenes; fullerenes replacement; organic conjugated polymers; perovskite solar cells; Perovskites; Photovoltaic cells; planar-heterojunction; Solar cells; Solar energy; Work functions
• ISSN: 1614-6832; 1614-6840
• DOI: 10.1002/aenm.201501534

An amino‐functionalized copolymer with a conjugated backbone composed of fluorene, naphthalene diimide, and thiophene spacers (PFN‐2TNDI) is introduced as an alternative electron transport layer (ETL) to replace the commonly used [6,6]‐Phenyl‐C61‐butyric acid methyl ester (PCBM) in the p–i–n planar‐heterojunction organometal trihalide perovskite solar cells. A combination of characterizations including photoluminescence (PL), time‐resolved PL decay, Kelvin probe measurement, and impedance spectroscopy is used to study the interfacial effects induced by the new ETL. It is found that the amines on the polymer side chains not only can passivate the surface traps of perovskite to improve the electron extraction properties, they also can reduce the work function of the metal cathode by forming desired interfacial dipoles. With these dual functionalities, the resulted solar cells outperform those based on PCBM with power conversion efficiency (PCE) increased from 12.9% to 16.7% based on PFN‐2TNDI. In addition to the performance enhancement, it is also found that a wide range of thicknesses of the new ETL can be applied to produce high PCE devices owing to the good electron transport property of the polymer, which offers a better processing window for potential fabrication of perovskite solar cells using large‐area coating method. The fullerene electron transport layer is replaced by a thickness‐insensitive ­conjugated polymer in p–i–n planar hetero­junction perovskite solar cells. The amines of polymer side chains can both passivate the surface traps of perovskite and reduce the work function of the metal cathode. With these dual functionalities, the resulting solar cells show 16.7% power conversion efficiency (PCE), which outperforms those based on fullerene interlayers.