B–N, B–O, and B–CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B‑Bromo-Carboranes

Carboranes are boron-rich molecules that can be functionalized through metal-catalyzed cross-coupling. Here, for the first time, we report the use of bromo-carboranes in palladium-catalyzed cross-coupling for efficient B–N, B–O, and unprecedented B–CN bond formation. In many cases bromo-carboranes o...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2016-07, Vol.138 (29), p.9081-9084
Main Authors: Dziedzic, Rafal M, Saleh, Liban M. A, Axtell, Jonathan C, Martin, Joshua L, Stevens, Simone L, Royappa, A. Timothy, Rheingold, Arnold L, Spokoyny, Alexander M
Format: Article
Language:English
Subjects:
catalysts
chemical reactions
organic compounds
palladium
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