Chitosan-bound pyridinedicarboxylate Ni(II) and Fe(III) complex biopolymer films as waste water decyanidation agents

• Published in: Carbohydrate polymers 2016-10, Vol.151, p.1235-1239
• Main Authors: Adewuyi, Sheriff, Jacob, Julianah Modupe, Olaleye, Oluwatoyin Omolola, Abdulraheem, Taofiq Olanrewaju, Tayo, Jubril Ayopo, Oladoyinbo, Fatai Oladipupo
• Format: Article
• Language: English
• Subjects: Biopolymer film and decyanidation; Carboxylic Acids - chemistry; Chitosan; Chitosan - chemistry; Cyanides - chemistry; Cyanides - isolation & purification; Iron - chemistry; iron(III); Nickel - chemistry; nickel(II); Organometallic Compounds - chemistry; Pyridinecarboxylate; Waste Water - chemistry; Water - chemistry; Water Pollutants, Chemical - chemistry; Water Pollutants, Chemical - isolation & purification; Water Purification - methods
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2016.06.070

•Chitosan bound pyridinedicarboxylate Ni(II) and Fe(III) complex biopolymer films were formed.•Removal of toxic CN− was greatly achieved with moderate dose of the films.•The anionic complexing mechanism is based on the stabilization and geometric conformation of chitosan-metal complexes. Chitosan is a biopolymer with immense structural advantage for chemical and mechanical modifications to generate novel properties, functions and applications. This work depicts new pyridinedicarboxylicacid (PDC) crosslinked chitosan-metal ion films as veritable material for cyanide ion removal from aqueous solution. The PDC-crosslinked chitosan-metal films (PDC-Chit–Ni(II) and PDC-Chit–Fe(III)) were formed by complexing PDC-crosslinked chitosan film with anhydrous nickel(II) and iron(III) chloride salts respectively. The PDC-Chit and its metal films were characterized employing various analytical and spectroscopic techniques. The FT-IR, UV–vis and the XRD results confirm the presence of the metal ions in the metal coordinated PDC-crosslinked chitosan film. The surface morphological difference of PDC-Chit-Ni(II) film before and after decyanidation was explored with scanning electron microscopy. Furthermore, the quantitative amount of nickel(II) and iron(III) present in the complex were determined using Atomic Absorption Spectrophotometer as 32.3 and 37.2μg/g respectively which portends the biopolymer film as a good complexing agent. Removal of cyanide from aqueous solution with PDC-Chit, PDC-Chit–Ni(II) and PDC-Chit–Fe(III) films was studied with batch equilibrium experiments. At equilibrium, decyanidation capacity (DC) followed the order PDC-Chit-Ni (II)≈PDC-Chit-Fe(III)>PDC-Chit. PDC-Chit-Ni(II) film gave 100% CN− removal within 40min decyanidation owing to favorable coordination geometry.