Preparation and properties of luffa fiber- and kenaf fiber-filled poly(butylene succinate-co-lactate)/starch blend-based biocomposites

Biodegradable poly(butylene succinate-co-lactate) (PBSL)/starch blends that contain various amounts of starch were prepared. In addition, luffa fiber (LF) and kenaf fiber (KF) were incorporated, individually, into PBSL/starch (70/30) blend to achieve biocomposites. The LF and KF were treated with Na...

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Bibliographic Details
Published in:Polymer testing 2016-04, Vol.50, p.191-199
Main Authors: Lai, Sun-Mou, Kao, Yu-Hsiang, Liu, Yu-Kuo, Chiu, Fang-Chyou
Format: Article
Language:English
Subjects:
Biocomposites
Blends
Crystallization
Dynamics
Fibers
Formations
Kenaf
Kenaf fiber
Luffa fiber
Physical properties
poly(butylene succinate-co-lactate)
Starch
Starches
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Summary:Biodegradable poly(butylene succinate-co-lactate) (PBSL)/starch blends that contain various amounts of starch were prepared. In addition, luffa fiber (LF) and kenaf fiber (KF) were incorporated, individually, into PBSL/starch (70/30) blend to achieve biocomposites. The LF and KF were treated with NaOH(aq) prior to their addition to the blend. The Young's modulus and flexural modulus of PBSL increased with the addition of starch and increased further after the formation of the biocomposites. The highest Young's modulus increment, which was found in the KF-added system, was up to a 2.2-fold increase compared with neat PBSL. The tensile/flexural/impact strength of PBSL declined after the formation of the blends. With the further addition of LF/KF, the said properties leveled off. The blends exhibited higher complex viscosity and dynamic storage modulus in the melt state than the neat PBSL, and the values further increased in the biocomposites. The crystallization temperature of PBSL slightly decreased in the blends. By contrast, the biocomposites showed an increment in PBSL crystallization temperature, from 73.0 °C (PBSL) to 75.3 °C (KF-added composite), thereby confirming the surface nucleation effect of LF/KF. The blends showed a higher degree of water absorption than PBSL. The formation of biocomposites led to an even higher degree of water absorption. The current approach of including LF/KF in the PBSL/starch blend to enhance the rigidity and biodegradability was advantageous in expanding the applications of PBSL.
ISSN:0142-9418
1873-2348
DOI:10.1016/j.polymertesting.2016.01.015