Fabrication of magnetically responsive HKUST-1/Fe3O4 composites by dry gel conversion for deep desulfurization and denitrogenation

• Published in: Journal of hazardous materials 2017-01, Vol.321, p.344-352
• Main Authors: Tan, Peng, Xie, Xiao-Yan, Liu, Xiao-Qin, Pan, Ting, Gu, Chen, Chen, Peng-Fei, Zhou, Jia-Yu, Pan, Yichang, Sun, Lin-Bing
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Denitrogenation; Desulfurization; Drying; Liquid phases; Magnetically responsive composites; Metal-organic frameworks; Nanoparticles; Porosity; Regeneration; Strategy
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2016.09.026

•DGC is developed to synthesize magnetically responsive MOF/Fe3O4 composites.•DGC simplifies synthetic procedures and minimizes solvent consumption.•The composites are used for adsorption desulfurization and denitrogenation.•The composites can be recycled efficiently by an external magnetic field. Selective adsorption by use of metal-organic frameworks (MOFs) is an effective method for purification of hydrocarbon fuels. In consideration that the adsorption processes proceed in liquid phases, separation and recycling of adsorbents should be greatly facilitated if MOFs were endowed with magnetism. In the present study, we reported for the first time a dry gel conversion (DGC) strategy to fabricate magnetically responsive MOFs as adsorbents for deep desulfurization and denitrogenation. The solvent is separated from the solid materials in the DGC strategy, and vapor is generated at elevated temperatures to induce the growth of MOFs around magnetic Fe3O4 nanoparticles. This strategy can greatly simplify the complicated procedures of the well-known layer-by-layer method and avoid the blockage of pores confronted by introducing magnetic Fe3O4 nanoparticles to the pores of MOFs. Our results show that the adsorbents are capable of efficiently removing aromatic sulfur and nitrogen compounds from model fuels, for example removing 0.62mmolg−1S and 0.89mmolg−1N of thiophene and indole, respectively. In addition, the adsorbents are facile to separate from liquid phases by use of an external field. After 6 cycles, the adsorbents still show a good adsorption capacity that is comparable to the fresh one.