Palladacycle catalysis: an innovation to the Suzuki-Miyaura cross-coupling reaction

Herein we report a Suzuki-Miyaura type cross-coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistry.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (44), p.17598-17601
Main Authors: Lucio-Martínez, Fátima, Adrio, Luis A, Polo-Ces, Paula, Ortigueira, Juan M, Fernández, Jesús J, Adams, Harry, Pereira, M Teresa, Vila, José M
Format: Article
Language:English
Subjects:
Aromatic compounds
Catalysis
Catalysts
Chemical reactions
Cross coupling
Halides
Metalorganic compounds
Palladium
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Summary:Herein we report a Suzuki-Miyaura type cross-coupling between an aryl halide and a functionalized boronic acid palladacycle in the absence of an external catalyst. This reaction is an unprecedented case of catalysis in palladium metallacycle chemistry.
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03542f