Dinuclear Metallacycles with Single M–X–M Bridges (X = Cl–, Br–; M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)): Strong Antiferromagnetic Superexchange Interactions

A series of monochloride-bridged, dinuclear metallacycles of the general formula [M2(μ-Cl)­(μ-L)2]­(ClO4)3 have been prepared using the third-generation, ditopic bis­(pyrazolyl)­methane ligands L = m-bis­[bis­(1-pyrazolyl)­methyl]­benzene (L m ), M = Cu­(II), Zn­(II), and L = m-bis­[bis­(3,5-dimethy...

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Bibliographic Details
Published in:Inorganic chemistry 2017-03, Vol.56 (5), p.2884-2901
Main Authors: Reger, Daniel L, Pascui, Andrea E, Foley, Elizabeth A, Smith, Mark D, Jezierska, Julia, Wojciechowska, Agnieszka, Stoian, Sebastian A, Ozarowski, Andrew
Format: Article
Language:English
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