Kinetics of indium dissolution from marmatite with high indium content in pressure acid leaching

• Published in: Rare metals 2017, Vol.36 (1), p.69-76
• Main Authors: Tian, Lei, Liu, Yan, Zhang, Ting-An, Lv, Guo-Zhi, Zhou, Shuang, Zhang, Guo-Quan
• Format: Article
• Language: English
• Subjects: Acid leaching; Agitation; Biomaterials; Chemistry and Materials Science; Energy; Indium; Leaching; Materials Engineering; Materials Science; Metallic Materials; Nanoscale Science and Technology; Oxygen; Partial pressure; Particle size; Physical Chemistry; Sulfuric acid
• ISSN: 1001-0521; 1867-7185
• DOI: 10.1007/s12598-016-0762-z

The kinetics of oxygen pressure acid leaching marmatite with high indium content was studied. The effects of particle size, agitation rate, temperature, H 2 SO 4 concentration, and oxygen partial pressure on leaching rate of indium were investigated. The results show that when the agitation rate is above 600 r·min −1 , its influence on indium leaching rate is insignificant. It is determined that the leaching rates increase with the increase in sulfuric acid concentration, temperature, partial oxygen pressure, and the decrease in particle size. Moreover, the results demonstrate that the process of indium leaching is controlled by interface chemical reaction, with apparent activation energy of 65.7 kJ·mol −1 . The apparent reaction orders of sulfuric acid and oxygen partial pressure are determined to be 0.749 and 1.260, respectively. The leaching reaction process follows shrinking unreacted core model. And finally, the kinetics model equation is established for indium.