A novel benzidine based Schiff base “turn-on” fluorescent chemosensor for selective recognition of Zn2

• Published in: Sensors and actuators. B, Chemical Chemical, 2017-03, Vol.241, p.1218-1223
• Main Authors: Kumar, Mukesh, Kumar, Amit, Singh, Mantu Kumar, Sahu, Sumanta K., John, Rohith P.
• Format: Article
• Language: English
• Subjects: Aluminum; Binding; Chemo-sensor; Detection limit; Emission; Fluorescence; Mathematical analysis; Metal ions; Recognition; Schiff base; Solvents; Zn2
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2016.10.008

[Display omitted] •A benzidine based Schiff base chemo-sensor show selective fluorescent emission upon binding Zn2+.•The chemo-sensor show high selectivity to Zn2+, compared other competing metal ions.•The sensor also operates over wide range with a lower fluorescent detection limit in the nano-molar range. A novel chemo-sensor based on diaminobenzidine (H2L) was synthesized and characterized. The chemo-sensor shows selective “turn-on” fluorescence response to Zn2+ ion over a variety of other competing metal ions such as Al3+, Mn2+, Fe3+, Co2+, Ni2+, Cu2+, and Cd2+. The strong fluorescent emission can be observed even at ppm level concentration of the probe in the presence of Zn2+ with over 54 fold intensity enhancement at 509nm. Similar fluorescence behaviour is also observed in a variety of solvents and solvent mixtures in the presence of zinc(II). The fluorescent emission is also detected when the H2L sample solution containing Zn2+ is exposed to UV radiation. The sensitive nature of fluorescent response of the probe to Zn2+ is gauged from the very low detection limit of 8.6×10−9M. The chemo-sensor H2L binds to zinc(II) in 1:1 stoichiometry as determined by Job's plot and the binding constant is calculated as 7.8×104M−1.