Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional...

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Published in:Chemical communications (Cambridge, England) England), 2015-02, Vol.51 (17), p.3582-3585
Main Authors: Yang, Ke, Wang, Yuqi, Chen, Xinyong, Kadi, Adnan A, Fun, Hoong-Kun, Sun, Hao, Zhang, Yan, Lu, Hongjian
Format: Article
Language:English
Subjects:
Aromatic compounds
Benzene Derivatives - chemistry
Benzoic Acid - chemistry
Catalysis
Functional groups
Molecular Structure
Nickel
Nickel - chemistry
Strategy
Substrates
Sulfides
Sulfides - chemical synthesis
Sulfides - chemistry
Tolerances
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container_end_page 3585
container_issue 17
container_start_page 3582
container_title Chemical communications (Cambridge, England)
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creator Yang, Ke
Wang, Yuqi
Chen, Xinyong
Kadi, Adnan A
Fun, Hoong-Kun
Sun, Hao
Zhang, Yan
Lu, Hongjian
description A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional group tolerance.
doi_str_mv 10.1039/c4cc10431e
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source Royal Society of Chemistry
subjects Aromatic compounds
Benzene Derivatives - chemistry
Benzoic Acid - chemistry
Catalysis
Functional groups
Molecular Structure
Nickel
Nickel - chemistry
Strategy
Substrates
Sulfides
Sulfides - chemical synthesis
Sulfides - chemistry
Tolerances
title Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes
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