Single-Site Cobalt Catalysts at New Zr12(μ3‑O)8(μ3‑OH)8(μ2‑OH)6 Metal–Organic Framework Nodes for Highly Active Hydrogenation of Nitroarenes, Nitriles, and Isocyanides

We report here the synthesis of a robust and porous metal–organic framework (MOF), Zr12-TPDC, constructed from triphenyl­dicarboxylic acid (H2TPDC) and an unprecedented Zr12 secondary building unit (SBU): Zr12(μ3-O)8­(μ3-OH)8­(μ2-OH)6. The Zr12-SBU can be viewed as an inorganic node dimerized from t...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2017-05, Vol.139 (20), p.7004-7011
Main Authors: Ji, Pengfei, Manna, Kuntal, Lin, Zekai, Feng, Xuanyu, Urban, Ania, Song, Yang, Lin, Wenbin
Format: Article
Language:English
Subjects:
amines
catalysts
cobalt
hydrogenation
nitriles
Online Access:Get full text
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