Volatiles in subduction zone magmas: concentrations and fluxes based on melt inclusion and volcanic gas data

• Published in: Journal of volcanology and geothermal research 2005-01, Vol.140 (1), p.217-240
• Main Author: Wallace, Paul J.
• Format: Article
• Language: English
• Subjects: Crystalline rocks; Earth sciences; Earth, ocean, space; Exact sciences and technology; Igneous and metamorphic rocks petrology, volcanic processes, magmas; Marine; melt inclusion; subduction zone; volatiles
• ISSN: 0377-0273; 1872-6097
• DOI: 10.1016/j.jvolgeores.2004.07.023

Owing to advances in microanalytical techniques over the last 15 years, there is a growing database on the volatile contents of subduction-related magmas as recorded in melt (glass) inclusions trapped in phenocrysts in volcanic rocks. Basaltic magmas from subduction zones show a wide range of water contents, ranging from as high as 6–8 to 3000 ppm, suggesting that no melt inclusions sample undegassed arc magmas. The Cl and S contents of arc basaltic magmas are greater than midocean ridge basalts, indicating that these volatiles are also recycled from subducted sediment and altered oceanic crust back into the mantle wedge. Comparison of the fluxes of volatiles subducted back into the mantle along subduction zones and returned from the mantle to the surface reservoir (crust, ocean, and atmosphere) via magmatism suggests that there is an approximate balance for structurally bound H 2O and Cl. In contrast, ∼50% of subducted C appears to be returned to the deep mantle by subduction, but uncertainties are relatively large. For S, the amount returned to the surface reservoir by subduction zone magmatism is only ∼15–30% of the total amount being subducted. Dacitic and rhyolitic magmas in arcs contain 1–6 wt.% H 2O, a range that overlaps considerably with the values for basaltic magmas. Either basaltic parents for these differentiated magmas are relatively H 2O-poor, or intermediate to silicic arc magmas form through open-system processes involving variable amounts of crustal melting, mixing with basalt and basaltic differentiates, and fluxing of CO 2-rich vapor from mafic magma recharged into silicic magma bodies. Consideration of H 2O–CO 2 relations and gaseous SO 2 emissions for intermediate to silicic arc magmas shows that such magmas are typically vapor-saturated during crystallization in the middle t