Palladium‐Catalyzed Mizoroki–Heck‐Type Alkenylation of Monoaryldialkylsulfoniums

Mizoroki–Heck‐type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts. Various combinations of monoarylsulfoniums and alkenes were adapted to the present reaction. Because monoaryldimethylsulfoniums were readily prepared from the corresponding aryl methyl...

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Published in:Chemistry, an Asian journal an Asian journal, 2018-09, Vol.13 (17), p.2397-2400
Main Authors: Uno, Daisuke, Minami, Hiroko, Otsuka, Shinya, Nogi, Keisuke, Yorimitsu, Hideki
Format: Article
Language:English
Subjects:
Alkenes
alkenylation
Aromatic compounds
aryl methyl sulfide
arylsulfonium
Chemistry
Palladium
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Yorimitsu, Hideki
description Mizoroki–Heck‐type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts. Various combinations of monoarylsulfoniums and alkenes were adapted to the present reaction. Because monoaryldimethylsulfoniums were readily prepared from the corresponding aryl methyl sulfides and methyl triflate, one‐pot alkenylation of aryl methyl sulfide could also be executed. Mizoroki–Heck‐type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts. Because monoaryldimethylsulfoniums were readily prepared from the corresponding aryl methyl sulfides and methyl triflate, one‐pot alkenylation of aryl methyl sulfide could also be executed.
doi_str_mv 10.1002/asia.201800489
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subjects Alkenes
alkenylation
Aromatic compounds
aryl methyl sulfide
arylsulfonium
Chemistry
Palladium
title Palladium‐Catalyzed Mizoroki–Heck‐Type Alkenylation of Monoaryldialkylsulfoniums
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