Structure of colloid particles in groundwaters on the territory of the Mayak production association and its impact on the colloid transport of radionuclides in subsoil environments

• Published in: Geochemistry international 2009-11, Vol.47 (11), p.1100-1106
• Main Authors: Malkovsky, V. I., Dikov, Yu. P., Kalmykov, S. N., Buleev, M. I.
• Format: Article
• Language: English
• Subjects: Earth and Environmental Science; Earth Sciences; Geochemistry
• ISSN: 0016-7029; 1556-1968
• DOI: 10.1134/S0016702909110056

Colloid particles were examined in groundwaters sampled at the large contamination area of the subsoil environment at the Mayak production association in the Southern Urals. Colloid particles were separated from groundwater samples by ultrafiltration, and their composition and structure were analyzed by X-ray photoelectron spectroscopy (XPS) and Auger spectroscopy (AS). Our results indicate that the chemical composition of the particles significantly varies at their surface and along their radii, from the peripheries to the cores of the particles. The data are used to estimate the possibility of utilizing properties of colloid particles contained in groundwaters (the composition, structure, and zeta potential of such particles) to numerically simulate the spreading of radioactive contamination with groundwaters with regard to the colloid mode of radionuclide transport. It is demonstrated that, along with transmitting electron spectroscopy (TEM) coupled with X-ray microprobe analysis and electron diffraction, the XPS and AS techniques make it possible to obtain information on heterogeneity in the distribution and modes of occurrence of various elements in colloid particles.