meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core o...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2019-06, Vol.17 (25), p.6131-6135
Main Authors: Halder, Nyancy, Sangeetha, Mohandas, Usharani, Dandamudi, Rath, Harapriya
Format: Article
Language:English
Subjects:
Aromatic compounds
Crystallography
Electrochemistry
NMR
Nuclear magnetic resonance
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Summary:A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core of heterocyclic macrocycles.
ISSN:1477-0520
1477-0539
DOI:10.1039/c9ob01062a