meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core o...

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Published in:Organic & biomolecular chemistry 2019-06, Vol.17 (25), p.6131-6135
Main Authors: Halder, Nyancy, Sangeetha, Mohandas, Usharani, Dandamudi, Rath, Harapriya
Format: Article
Language:English
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Aromatic compounds
Crystallography
Electrochemistry
NMR
Nuclear magnetic resonance
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cited_by cdi_FETCH-LOGICAL-c315t-a73cff389d61ef1f3bc5a16a64d46fc58e7d827ec9c8a9691b63207e037c7a473
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creator Halder, Nyancy
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description A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core of heterocyclic macrocycles.
doi_str_mv 10.1039/c9ob01062a
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Aromatic compounds
Crystallography
Electrochemistry
NMR
Nuclear magnetic resonance
Substitutes
title meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization
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